Hydrogen is the simplest and most abundant element in the universe. It is a primary product of the Big Bang and continues to be produced through stellar nuclear fusion. We owe most of the energy on our planet to hydrogen because the Sun’s nuclear fusion process converts hydrogen to helium releasing large amounts of energy.
Almost all energy sources contain carbon and hydrogen, although, as time passes, a declining ratio of carbon and an increasing hydrogen ratio are introduced into the energy mix. For this reason, renewable hydrogen is the final step of an energy shift away from carbon that has a history of 200 years - since the industrial revolution made use of coal.
Hydrogen can be found in stars that use it as fuel to produce energy and in “empty” spaces between the stars. On Earth, it does not typically exist by itself in nature and must be produced from compounds that contain it, for instance, from water (H2O). Hydrogen is believed to be one of three elements produced in the Big Bang and the only element that can exist without neutrons. We owe most of the energy on our planet to hydrogen because the Sun’s nuclear fusion process converts hydrogen to helium releasing large amounts of energy. Hydrogen was used as a fuel for the rocket (Saturn V) that carried the first astronauts to the moon.
Hydrogen can be produced via several methods. Each method has its own energy requirements, costs and environmental considerations. The choice of production method depends on factors such as the availability of feedstock, energy source, scale of production and desired environmental impact.
This is the most common method of industrial hydrogen production, accounting for the majority of global hydrogen production. It involves reaction of natural gas (methane, CH4) with high-temperature steam in the presence of a catalyst. The reaction produces hydrogen gas (H2) and carbon monoxide (CO). The carbon monoxide is then reacted with additional steam in a process called the water-gas shift reaction to convert it into more hydrogen and carbon dioxide (CO2).
Electrolysis is a process that uses an electric current to split water (H2O) into hydrogen and oxygen. Water electrolysis requires a source of electricity, which can come from renewable sources such as solar, wind or hydro-electric power. This method is known as “water electrolysis” and can be an environmentally friendly way to produce hydrogen when powered by renewable energy.
For Cleanergy, green hydrogen is produced through a process called electrolysis, which utilises renewable energy sources to generate hydrogen without carbon emissions. Here's how it works:
Hydrogen has no colour. The colour of the hydrogen refers to its production process.
Cleanergy will produce green hydrogen, where the electricity used in the electrolysis process is sourced from solar energy, ensuring that the hydrogen production process is carbon-free and environmentally sustainable. This makes green hydrogen a promising and clean energy carrier for various applications, including industries, transportation and energy storage.
Since hydrogen is a very light gas, its storage requires the necessary attention. For 1kg of hydrogen you need a volume of 11m3 at ambient conditions. Given that this quantity can allow a H2 powered vehicle to travel 100km, it is easy to see why storing it in its natural form is so complicated.
At hydrogen production plants, small amounts of hydrogen are often stored at low pressure, 40 bar. At our Cleanergy site, a low pressure buffer tank is placed between the electrolyser and compressors. Its goal is to deliver hydrogen at a steady pressure to the compressors to ensure a continuous and smooth process. This buffer is 10 m high with a outer diameter of 2.5 m. 127kg of hydrogen can be stored inside this 40m³ tank. It’s the hydrogen production of a few hours at our site in Walvis Bay.
Compressed hydrogen is stored as a gas under high pressure, typically ranging from 200 to 700 bar or more. Specialised containers made of materials like steel or composites are used to withstand these extreme pressures. Valves and fittings allow for filling, usage and connections to hydrogen distribution systems. Safety measures are essential due to hydrogen’s flammability and high pressure, making compressed hydrogen suitable for applications such as fuelling vehicles and industrial processes.
Liquid hydrogen is stored at extremely low temperatures and under pressure to maintain its liquid state. It requires specialised tanks with thick insulation to prevent evaporation and maintain temperatures around -253°C. Safety precautions are vital due to its extreme cold and flammability. While liquid hydrogen offers high energy density, it comes with high production and storage costs and is mainly used in applications like rocket propulsion and certain specialised industries.
Hydrogen must be transported from the production point to the point of use and be handled within refuelling stations or stationary power facilities. There are three different delivery methods: gaseous hydrogen delivery, cryogenic liquid hydrogen delivery and new solid or liquid hydrogen organic carriers. The present solutions for hydrogen transportation are divided into road and rail transportation and hydrogen pipelines. Hydrogen ocean transportation is also emerging as a promising alternative that will be available in the near future.
The transportation of hydrogen by road and rail can be carried out using compressed gas cylinders via tube trailers of approximately 2000L, with a pressure of around 180-250 bar, or as a liquid in tanktainers (specialised containers for transporting liquid hydrogen) that range from 20,000 to 50,000L, with pressure levels of 6-10 bar and extremely low temperatures (-252.8 °C).
The hydrogen pipeline network is limited and based on natural gas technology. Western Europe owns the longest pipeline network: about 1500km that covers part of France and the Benelux countries. The operating pressures are normally between 10 and 85 bar, with diameters between 25 and 30cm.
Hydrogen transport by ship is technically possible for larger distances where pipelines are not an option. Because of its low energy density by volume, gaseous hydrogen is best converted into a more energy-dense liquid before being loaded onto a ship. Transportation of liquid hydrogen is extremely difficult, due to the need to maintain - 253°C during the entire trip. This low temperature makes all equipment very expensive.
Hydrogen and green ammonia are distinct energy carriers with unique characteristics:
Hydrogen (H₂): This elemental gas, composed of two hydrogen atoms, is colourless, odourless and highly flammable. It primarily serves as a clean energy carrier and can be directly employed in fuel cells for electricity generation or reconverted into electricity and water as needed.
Ammonia (NH₃): Ammonia is a compound formed by one nitrogen atom bonded to three hydrogen atoms. While traditionally used in agriculture for fertilisers, green ammonia is emerging as a potential energy carrier. It's produced through the synthesis of nitrogen and hydrogen, often derived from green hydrogen generated by renewable sources. Ammonia's advantage lies in its ability to store hydrogen in a denser form, facilitating transportation and handling. However, it's worth noting that ammonia production, particularly via the Haber-Bosch process, is a major source of industrial hydrogen demand. This process combines nitrogen from the air with hydrogen to produce ammonia, making it vital in the agricultural sector. Nonetheless, its environmental impact includes potential nitrogen oxide emissions during combustion, necessitating emission control technologies.
With its maritime business unit, CMB.TECH is a firm advocate for the pivotal role of green hydrogen (for smaller vessels) and green ammonia (for larger ships) in the essential decarbonisation of the shipping industry. Our marine division is at the forefront of this transformation, actively involved in the construction, ownership, operation and design of an extensive fleet of low and zero-carbon ships. This diverse portfolio encompasses dry bulk vessels, container carriers, chemical tankers, tugboats, crew transfer vessels for the offshore wind industry, ferries, barges and more.
Visit CMB.TECH’s website for more information: Marine | CMB.TECH
CMB.TECH also has an industry business unit, delivering adaptable dual fuel platforms tailored for heavy-duty applications. The dedication to hydrogen solutions stems from our pledge to provide affordable, reliable and sustainable solutions that actively reduce emissions and diminish our clients' environmental impact. We have established partnerships with leading engine manufacturers to ensure the highest quality of our applications.
Our advanced technology allows us to convert conventional diesel engines into dual fuel or mono fuel engines, granting clients both flexibility and cost-effectiveness. Our engine range includes high-speed options ideal for smaller-scale applications, alongside medium-speed engines designed for marine and heavy-duty applications.
Visit CMB.TECH’s website for more information: Industry | CMB.TECH
Within H₂ Infra, CMB.TECH designs, develops and operates the essential technology and infrastructure necessary for the production of green hydrogen and ammonia.
They pay special attention to hydrogen and ammonia storage, covering every aspect of the value chain to ensure the delivery of cleaner fuels for the future.
In 2019, CMB.TECH opened the first maritime and public hydrogen refuelling station, equipped with a 1.2MW PEM electrolyser and a 500bar tube trailer filling station.
Visit CMB.TECH’s website for more information: H₂ infra | CMB.TECH
Cleanergy Namibia is one of the main projects within the H₂ Infra unit, with a hydrogen production plant, a refuelling station and a Hydrogen Academy.
The project covers full circle from production to consumer
Hydrogen, much like other fuels, possesses flammable characteristics like natural gas and gasoline, necessitating careful handling to ensure safety.
Specific properties of hydrogen include a low ignition energy, flammability within a broad range (4-75% concentration, in contrast to gasoline's 1.3% - 7.1%), extreme lightness (being 14 times lighter than air, facilitating rapid gas dispersion) and a notably low energy density at atmospheric pressure.
In terms of safety, the primary focus for hydrogen equipment lies in high-pressure conditions. All components undergo rigorous testing and certification, maintaining a large safety margin. Notably, under atmospheric pressure and temperature, hydrogen proves to be a safer fuel option compared to gasoline, LPG or natural gas.
The Cleanergy project includes a 10-hectare solar park with a hydrogen production facility equipped with a 5 MW PEM electrolyser and a 5 MWh battery. This plant - the first green hydrogen production facility of its kind in Africa - directly harnesses solar energy to produce hydrogen, which is then made available at the public hydrogen refuelling station for trucks and heavy-duty applications.
The electrolyser will produce green hydrogen based on the electricity input from the solar park and the energy stored in the BESS (Battery Energy Storage System). A hybrid control system will manage the electricity flows to ensure stable green hydrogen production and a stable mini-grid. This set-up is unique worldwide and will provide Cleanergy with the necessary knowledge for its future developments. The site is developed as a flexible project that can easily be extended with other activities and technologies. This open approach supports Cleanergy's ambition to make it a hotspot for upskilling local people.
Cleanergy Solutions Namibia is a joint venture of Ohlthaver & List and CMB.TECH
Since 2021, Ohlthaver & List (O&L) and CMB.TECH have been working together to leverage their unique expertise. Both companies have a history of more than 100 years of being entrepreneurial and innovative. Today, the highlight of the joint efforts is the realisation of Cleanergy’s first project, the hydrogen production and refuelling station.
O&L with its Nexentury subsidiary is a solar pioneer bringing its extensive knowledge and regional presence, while CMB.TECH contributes with its advanced hydrogen expertise and hydrogen powered applications. This collaboration between two solid family-owned companies stems from a shared vision to deliver a remarkable and impactful project in Namibia.
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula NH3. It is present in the environment as a result of natural processes and industrial activity, including certain types of intensive farming.
Currently, about 200 Mt/y of ammonia is manufactured globally, making it the world’s second most commonly produced chemical. From this, around 20Mt is traded around the globe. An important network of ports, pipelines and storage facilities dedicated to ammonia supports this trade.
A typical mid sized gas carrier can hold 40,000m3. As a base material for fertilisers, ammonia literally helps to put food on our table. Today, roughly 80% of the annually produced ammonia is used for fertiliser production. Ammonia is a key ingredient in nitrogen-based fertilisers. It’s used to provide plants with essential nitrogen nutrients for growth. Ammonia can be applied directly to the soil or mixed with other components to create various types of fertilisers.
Besides being used as a fertiliser, ammonia is also used in a lot of other applications like refrigerants, cleaning agents or even sport shoes. In the mining sector, ammonia derivates are used as explosives or as a leaching agent to extract valuable metals from ores. Ammonia leaching involves mixing ammonia (NH3) with the ore concentrate to create a solution containing metal ions. This solution is then processed to separate and recover the desired metals.
Ammonia requires special purpose infrastructure, including pipelines, tanks and facilities for maritime bunkering. At present, nearly 8,000 kilometers of ammonia pipeline run worldwide, along with 38 export and 88 receiving terminals.
Most ammonia pipelines are short. Although Europe, for example, has 25 pipelines, most are less than 10 km in length and only two are 25 km or longer. However, the US has several major trunk lines totalling nearly 5000 km and Russia has built a 2400 km pipeline.
Pipeline transport of liquid ammonia is a safe, low risk and, once installed, cost-effective mode of transporting ammonia between locations. Overall, ammonia pipelines appear to have an excellent safety record-roughly 2 times better than other pipelines and 7–8 times better than other forms of bulk transportation (NuStar, 2021 based on 2019 Bureau of Labor Statistics studies).
The widespread use of ammonia has led to a mature understanding of the safe handling of ammonia transportation and distribution and to appropriate risk management methods within these application areas. It has also led to an understanding of the environmental impacts of ammonia in these use cases. However, if low-carbon ammonia is adopted into new application areas, such as power generation and maritime fuels, new potential risks to human health and the environment may arise. These risks will require careful attention and management.
On 4 August 2020, a large amount of ammonium nitrate stored at the Port of Beirut in the capital city of Lebanon exploded. Cleanergy Solutions Namibia will not produce or store ammonium nitrate in Namibia, only ammonia will be produced.
Like other fuels, ammonia can burn in air. This poses risks when ammonia is transported and/or stored in enclosed environments, such as industrial buildings.
Pure anhydrous ammonia must reach concentrations of at least 15% in air for combustion to occur, which is much higher than methane (4.4%). As a result, the risk of unintended fires or explosions associated with ammonia leaks is lower than with methane and most other hydrocarbon fuels.
In the presence of a slow leak, people will easily detect increased concentrations of ammonia in air long before they rise to levels that pose major health hazards, allowing them to take action to leave the area, dilute with fresh air and/or address the source of the leak. In rare industrial accidents, ammonia has been released at sufficiently high rates that it cannot be diluted before workers or other populations are exposed to unsafe concentrations.
20 - 50ppm • Detectible odour
50 - 100ppm • No impairment of health for prolonged exposure
400 - 700ppm • Severe irritation, no lasting effects after short exposure
2000 - 3000ppm • Dangerous, less than 1/2h exposure can be fatal
5000 - 10000ppm • Rapidly fatal
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula NH3. It is present in the environment as a result of natural processes and industrial activity, including certain types of intensive farming.
Grey ammonia is produced from natural gas and air. With a process called Steam Methane Reforming natural gas is cracked to hydrogen. During this process CO2 is emitted to atmosphere. During several purification steps a purified mixture of hydrogen (H2) and nitrogen (N2) is obtained called synthesis gas. The synthesis gas is compressed and heated to convert hydrogen (H2) and nitrogen (N2) to ammonia (NH3). This ammonia is then liquified and separated from the remaining synthesis gas and pumped to the ammonia storage tanks.
Blue ammonia adds carbon capture to conventional hydrogen production from fossil fuels. Adding carbon capture to steam methane reforming (SMR) is relatively inexpensive for approximately two-thirds of the total CO2 emissions (which are already separated during production) but is significantly more expensive for the remaining CO2 emissions. The captured CO2 is then liquified and transported to a long term storage.
The production of green ammonia also uses the Haber-Bosch process to convert hydrogen and nitrogen into ammonia, however the hydrogen is coming from water electrolysis instead of steam methane reforming, reducing the CO2 emissions to zero. The production of electrolyser based ammonia is not new. Until 1991 an electrolyser based ammonia plant was operated in Norway using a 155MW electrolyser. The plant used hydropower as renewable power source. The plant was shut down due to the cost benefit of steam-methane reforming based ammonia plants.
The main contributor in the energy requirements of green ammonia is the electricity needed to produce green hydrogen. As the ammonia synthesis reaction is exothermic, a lot of waste heat is generated that can be recuperated to produce electricity with steam turbines. However even using this recuperated electricity, the net power requirements of the synthesis loop is negative due to the production of nitrogen and pressurise the system.
Ammonia can be stored as a liquid at more moderate conditions compared to hydrogen. Large quantities of ammonia are stored at -33°C and atmospheric pressure in tanks of up to 50,000 ton. Large ammonia tanks have a double wall as a protective measure to decrease the risk of a release to atmosphere.
Ammonia can be stored in pressurised vessels at ambient temperature and pressures up to 15 bar. This storage technology imposes additional safety risks because a sudden rupture can shoot ammonia over 5 meters from the point of release. Because of this, Cleanergy Solutions Namibia will not use this technology for large volumes.
Liquid anhydrous ammonia is almost completely water free, while aqueous ammonia is a water based solution that contains up to 25% ammonia. Aqueous ammonia can be used as a cleaning agent or in the waste water industry.
Ammonia is a hydrogen carrier, just like diesel and the molecule is formed by 1x nitrogen atom and 3x hydrogen atoms.
Much of the interest in ammonia as a clean-fuel solution is based on ammonia’s physical and chemical properties. These properties make it relatively easy to store and tranship the molecule. Ammonia is also one of the few synthetic fuels that does not contain carbon. Use of ammonia, either through combustion or conversion, releases no greenhouse gases. One cubic meter of ammonia has 4 times more stored energy than an equivalent volume of pressurised hydrogen. Also, compared to liquid hydrogen, the storage properties of ammonia are moderate. This makes ammonia a very suitable fuel.
It’s estimated that renewable ammonia could represent as much as 43% of the energy mix for shipping in 2050, which would imply the use of about 183 Mt of renewable ammonia for international shipping alone – a comparable amount to today’s global ammonia production. If the international shipping sector were a country, it would be the sixth or seventh-largest CO2 emitter, comparable to Germany.
As with most alternative fuels for shipping, the costs for producing and employing ammonia are high in comparison to fossil fuel alternatives with no emission abatement. However, these costs would decrease significantly by 2050, making the lower cost estimates even cheaper than the VLSFO market price. The biggest driver is currently the cost of the renewables and the electrolyser. This is expected to drop in the near future.
Since hydrogen is the smallest and lightest molecule in the universe, it is not easily stored in large quantities. High pressured vessels or cryogenic tanks are required, making it only economical for smaller storage sizes. Ammonia is in this respect a good solution as carrier for hydrogen as it is easier to store, meaning that ammonia can be used as a more dense energy carrier. The energy density per volume of ammonia is 35% higher compared to liquid hydrogen, while the storage is just -33°C compared to the cryogenic requirement for liquid hydrogen of -253°C.
After trans-shipment, ammonia can be converted back to hydrogen via a thermo-catalytic process also known as ammonia cracking. This process requires energy input and results in inevitable energy loss. Typically, after ammonia cracking, the hydrogen stream will be harvested and used for further applications and the nitrogen stream will be directly vented to the atmosphere.
Many of the proposed novel applications of low carbon ammonia are based on combustion. Compared to carbon-containing synthetic fuels (e.g., methanol, biodiesel, synthetic methane), ammonia combustion is carbon-free with no direct greenhouse gas effect from CO2. Although ammonia combustion is a good solution from a sustainability point of view, it has some challenges which need the required attention. When using ammonia, combustion there are two things to be aware of.
Ammonia slip results from the difficulty of maintaining stable combustion, which can result in uncombusted ammonia being directly emitted with exhaust gas. The formation of nitrous oxide and nitrogen oxide results from complex combustion chemistry. Applied research is required to address these topics. CMB.TECH and the Swiss marine power company WinGD have signed an
agreement on the development of ammonia-fuelled two stroke engines.
First, ammonia is harder to ignite than hydrogen and hydrocarbon fuels because of its relatively high auto-ignition temperature. In many cases, this can be addressed by initiating combustion with a more easily ignited fuel and then transitioning to pure ammonia fuel. Ammonia combustion in furnaces is currently being tested with coal co-firing in Japan.
Industrial processes with furnaces typically use enriched oxygen (O2) or multi-stage air injection to address the ignition and combustion challenges. In all cases, this adds complexity to the engine/furnace design and potentially to fuel management.
CMB.TECH believes that green hydrogen (for small ships)and green ammonia (for large ocean going ships) canplay an important role to decarbonize the shippingindustry.
The integration of the drivetrain, the storage and thebunkering of hydrogen and ammonia, is implemented witha diverse and experienced in-house engineering team inpartnership with Original equipment manufacturer andshipyards.
CMB is already building a future proof fleet with ammoniaClass Approval including bulk carriers, chemical tankersand container vessels on order, allowing a future retrofitfor using ammonia as a fuel without losing cargo capacity.
Cleanergy Solutions Namibia develops green hydrogen and ammonia solutions for a sustainable future.
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